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Continuous biohydrogen production from diluted molasses in an anaerobic contact reactor

Sheng CHANG, Jianzheng LI, Feng LIU

《环境科学与工程前沿(英文)》 2011年 第5卷 第1期   页码 140-148 doi: 10.1007/s11783-010-0258-2

摘要: An anaerobic contact reactor (ACR) system comprising a continuous flow stirred tank reactor (CSTR) with settler to decouple the hydraulic retention time (HRT) from solids retention time (SRT) was developed for fermentative hydrogen production from diluted molasses by mixed microbial cultures. The ACR was operated at various volumetric loading rates (VLRs) of 20–44 kgCOD·m ·d with constant HRT of 6 h under mesophilic conditions of 35°C. The SRT was maintained at about 46–50 h in the system. At the initial VLR of 20 kgCOD·m ·d , the hydrogen production rate dropped from 22.6 to 1.58 L·d as the hydrogen was consumed by the hydrogentrophic methanogen. After increasing the VLR to 28 kgCOD·m ·d and discharging the sludge for 6 consecutive times, the hydrogentrophic methanogens were eliminated, and the hydrogen content reached 36.4%. As the VLR was increased to 44 kgCOD·m ·d , the hydrogen production rate and hydrogen yield increased to 42.1 L·d and 1.40 mol H ·molglucose-consumed , respectively. The results showed that a stable ethanol-type fermentation that favored hydrogen production in the reactor was thus established with the sludge loading rate (SLR) of 2.0–2.5 kgCOD·kgMLVSS ·d . It was found that the ethanol increased more than other liquid fermentation products, and the ethanol/acetic acid (mol/mol) ratio increased from 1.27 to 2.45 when the VLR increased from 28 to 44 kgCOD·m ·d , whereas the hydrogen composition decreased from 40.4% to 36.4%. The results suggested that the anaerobic contact reactor was a promising bioprocess for fermentative hydrogen production.

关键词: fermentative hydrogen production     anaerobic contact reactor (ACR)     sludge loading rate (SLR)     butyric acid-type fermentation     ethanol-type fermentation    

Start-up of PN-anammox system under low inoculation quantity and its restoration after low-loading rate

Guoliang Zhang, Liang Zhang, Xiaoyu Han, Shujun Zhang, Yongzhen Peng

《环境科学与工程前沿(英文)》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1324-z

摘要: Abstract • PN-A was start-up under low inoculation amount and a higher NRR was achieved. • PN-anammox system was successfully restored by aggressive sludge discharge. • Increase in granular sludge was the important factor to rapid recovery. • Enrichment of AOB and AnAOB in granular sludge favors the stable operation. Partial nitritation (PN)-anaerobic ammonium oxidation (anammox) is a promising pathway for the biological treatment of wastewater. However, the destruction of the system caused by excessive accumulation of nitrate in long-term operation remains a challenge. In this study, PN-anammox was initialized with low inoculation quantity in an air-lift reactor. The nitrogen removal rate of 0.71 kgN/(m3·d) was obtained, which was far higher than the seed sludge (0.3 kgN/(m3·d)). Thereafter, excess nitrate build-up was observed under low-loading conditions, and recovery strategies for the PN-anammox system were investigated. Experimental results suggest that increasing the nitrogen loading rate as well as the concentration of free ammonium failed to effectively suppress the nitrite oxidation bacteria (NOB) after the PN-anammox system was disrupted. Afterwards, effluent back-flow was added into the reactor to control the up-flow velocity. As a result, an aggressive discharge of sludge that promoted the synergetic growth of functional bacteria was achieved, leading to the successful restoration of the PN-anammox system. The partial nitritation and anammox activity were in balance, and an increase in nitrogen removal rate up to 1.07 kgN/(m3·d) was obtained with a nitrogen removal efficiency of 82.4% after recovery. Besides, the proportion of granular sludge (over 200 mm) increased from 33.67% to 82.82%. Ammonium oxidation bacteria (AOB) along with anammox bacteria were enriched in the granular sludge during the recovery period, which was crucial for the recovery and stable operation of the PN-anammox system.

关键词: PN-anammox     Granular sludge     Excess nitrate build-up     Recovery strategy for partial nitrification     Aggressive discharge of sludge    

Microbial community dynamics at high organic loading rates revealed by pyrosequencing during sugar refinery

Liguo Zhang, Qiaoying Ban, Jianzheng Li

《环境科学与工程前沿(英文)》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1045-8

摘要:

High strength sugar refinery wastewater was treated in a mesophilic UASB.

Pyrosequencing reveals microbial community succession with OLR increase.

Diversity of microbial communities in OLR12 is much higher than those in OLR36 and OLR54.0 kgCOD/(kg VSS·d).

Fermentative bacteria could deal with increasing OLR through the increase of microbial diversity and quantity.

Hydrogen-producing acotogens and methanogens mainly coped with high OLR shocks by increasing the quantity of community

关键词: Upflow anaerobic sludge blanket     Sugar refinery wastewater     Organic loading rate     Pyrosequencing     Microbial community structure    

Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

《环境科学与工程前沿(英文)》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1595-7

摘要:

● Mechanical behavior of MBT waste affected by loading rate was investigated.

关键词: Mechanically and biologically treated waste     Landfill     Triaxial test     Loading rate     Axial strain     Shear strength parameter    

Achievement of high rate nitritation with aerobic granular sludge reactors enhanced by sludge recirculation

Zulkifly JEMAAT,Josep Anton TORA,Albert BARTROLI,Julián CARRERA,Julio PEREZ

《环境科学与工程前沿(英文)》 2015年 第9卷 第3期   页码 528-533 doi: 10.1007/s11783-014-0641-5

摘要: A ratio control strategy has been used to demonstrate the feasibility of this automatic control procedure for the achievement of stable full and partial nitritation. The control strategy assured constant ratio between the dissolved oxygen (DO) and the total ammonia nitrogen (TAN) concentrations in the bulk liquid of aerobic granular sludge reactors operating in continuous mode. Three different set-ups with different reactor capacities were used (3, 110, and 150 L). High strength synthetic wastewaters and reject water were tested with similar performance. Achieved nitrogen loading rates ranged between 0.4 and 6.1 kgN·m ·d , at temperatures between 20°C and 30°C. Granular sludge and nitritation were stable in the long term continuous operation of the reactors. Suitable stable effluent for Anammox has been obtained using the desired TAN setpoint (i.e. 50% of influent ammonium oxidation). An existing biofilm model developed incorporating the implemented control loops and validated in a previous publication was used to investigate the effects of the ammonium concentration of the influent and the biofilm density on the achievement of full nitritation. The model demonstrated how sludge recirculation events led to a stable and significant increase of the biomass concentration in the reactor, which in turn resulted in the achievement of high nitrogen loading rates, due to the action of the control strategy. The model predicted an enhancement of stable full nitritation at higher ammonium concentrations in the influent. Poor influence of the biofilm density in the achievement of full nitritation was predicted with the model.

关键词: partial nitrification     reject water     high strength ammonium wastewater     closed-loop control    

Modification of the activated sludge model for chemical dosage

Shuai MA,Siyu ZENG,Xin DONG,Jining CHEN,Gustaf OLSSON

《环境科学与工程前沿(英文)》 2015年 第9卷 第4期   页码 694-701 doi: 10.1007/s11783-014-0732-3

摘要: Full-scale experiments have been carried out to adapt the activated sludge model ASM2d to include the influence of metal dosage (Fe and Al ) for phosphorus removal. Phosphorus removal rates, nitrification rates, as well as pH and sludge settling performance, were evaluated as functions of the metal dosages. Furthermore, models relating certain parameters to the dosage of chemicals have been derived. Corresponding parameters in the ASM2d and the secondary settler models, included in the Benchmark Simulation Model No 1 (BSM1), have been modified to take the metal influence into consideration. Based on the effluent limits and penalty policy of China, an equivalent evaluation method was derived for the total cost assessment. A large number of 300-day steady-state and 14-day open-loop dynamic simulations were performed to demonstrate the difference in behavior between the original and the modified BSM1. The results show that 1) both in low and high mole concentrations, Fe addition results in a higher phosphorus removal rate than Al ; 2) the sludge settling velocity will increase due to the metal addition; 3) the respiration rate of the activated sludge is decreased more by the dosage of Al than Fe ; 4) the inhibition of Al on the nitrification rate is stronger than that of Fe ; 5) the total operating cost will reach the minimum point for smaller dosages of Fe , but always increase with Al addition.

关键词: chemical precipitation     benchmark simulation model     phosphorus removal     respiratory rate     sludge settling     activated sludge model    

Reconsideration on the effect of nitrogen on mixed culture polyhydroxyalkanoate production toward high organic loading

Zhiqiang Chen, Lizhi Zhao, Ye Ji, Qinxue Wen, Long Huang

《环境科学与工程前沿(英文)》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1135-2

摘要:

Effect of nitrogen on mixed culture PHA production was reconsidered.

Enrichment history of PHA accumulating culture was discussed.

Higher PHA content and biomass growth were achieved in presence of nitrogen.

Enrichment strategy toward higher PHA accumulation was investigated.

Microbial community succession in PHA accumulation phase was investigated.

关键词: Polyhydroxyalkanoate (PHA)     Organic loading rate     Nitrogen content     Biomass growth     Enrichment history    

Concept and application of anaerobic suspended granular sludge bed (SGSB) reactor for wastewater treatment

Mingxia ZHENG,Zhong YAN,Jiane ZUO,Kaijun WANG

《环境科学与工程前沿(英文)》 2014年 第8卷 第5期   页码 797-804 doi: 10.1007/s11783-013-0597-x

摘要: Bed expansion serves an important function in the design and operation of an upflow anaerobic reactor. An analysis of the flow pattern of expanded granular sludge bed (EGSB) reactors shows that most EGSB reactors do not behave as expanded bed reactors, as is widely perceived. Rather, these reactors behave as fluidized bed reactors based on the classic chemical reactor theory. In this paper, four bed expansion modes, divided as static bed, expanded bed, suspended bed, and fluidized bed, for bioreactors are proposed. A high-rate anaerobic suspended granular sludge bed (SGSB) reactor was then developed. The SGSB reactor is an upflow anaerobic reactor, and its expansion degree can be easily controlled within a range to maintain the suspended status of the sludge bed by controlling upflow velocity. The results of the full-scale reactor confirmed that the use of SGSB reactors is advantageous. The full-scale SGSB reactor runs stably and achieves high COD removal efficiency (about 90%) at high loading rates (average 40 kg-COD·m ·d , maximum to 52 kg-COD·m ·d ) based on the SGSB theory, and its expansion degree is between 22% and 37%.

关键词: expansion characteristic     high-rate bioreactor     anaerobic suspended granular sludge bed     expanded granular sludge bed reactor    

Performance of soft-hard-soft (SHS) cement based composite subjected to blast loading with consideration

Jun WU,Xuemei LIU

《结构与土木工程前沿(英文)》 2015年 第9卷 第3期   页码 323-340 doi: 10.1007/s11709-015-0301-2

摘要: This paper presents a combined experimental and numerical study on the damage and performance of a soft-hard-soft (SHS) multi-layer cement based composite subjected to blast loading which can be used for protective structures and infrastructures to resist extreme loadings, and the composite consists of three layers of construction materials including asphalt concrete (AC) on the top, high strength concrete (HSC) in the middle, and engineered cementitious composites (ECC) at the bottom. To better characterize the material properties under dynamic loading, interface properties of the composite were investigated through direct shear test and also used to validate the interface model. Strain rate effects of the asphalt concrete were also studied and both compressive and tensile dynamic increase factor (DIF) curves were improved based on split Hopkinson pressure bar (SHPB) test. A full-scale field blast test investigated the blast behavior of the composite materials. The numerical model was established by taking into account the strain rate effect of all concrete materials. Furthermore, the interface properties were also considered into the model. The numerical simulation using nonlinear finite element software LS-DYNA agrees closely with the experimental data. Both the numerical and field blast test indicated that the SHS composite exhibited high resistance against blast loading.

关键词: high strength concrete (SHS)     engineered cementitious composite     interface     blast test     strain rate effect    

Shear-critical reinforced concrete columns under various loading rates

Witarto WITARTO,Liang LU,Rachel Howser ROBERTS,Y. L. MO,Xilin LU

《结构与土木工程前沿(英文)》 2014年 第8卷 第4期   页码 362-372 doi: 10.1007/s11709-014-0083-y

摘要: This paper presents an experimental study of shear-governed reinforced concrete columns subjected to different loading rates. Four typical short columns were tested cyclically with loading rate of 0.05, 1, 3, and 5 Hz, simulating seismic load. Test result indicated that the loading rate does not affect the column behavior when the rate is up to 5 Hz. Furthermore, Carbon Nano-Fiber Aggregates (CNFAs) were utilized as internal sensors to detect the damage in the column. The test result shows that the CNFAs work well sensing the structural behavior. The CNFA output was further quantitatively correlated to the structural damage level. Finally, a finite element analytical model was constructed to describe the behavior of short columns with shear failure. The analytical model successfully modeled the cyclic loading test results.

关键词: reinforced concrete columns     shear failure     loading rate     Carbon Nano-Fiber Aggregates (CNFAs)     finite element analysis     OpenSees    

enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial loading

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

《结构与土木工程前沿(英文)》 2020年 第14卷 第6期   页码 1531-1544 doi: 10.1007/s11709-020-0675-7

摘要: Some of the current concrete damage plasticity models in the literature employ a single damage variable for both the tension and compression regimes, while a few more advanced models employ two damage variables. Models with a single variable have an inherent difficulty in accounting for the damage accrued due to tensile and compressive actions in appropriately different manners, and their mutual dependencies. In the current models that adopt two damage variables, the independence of these damage variables during cyclic loading results in the failure to capture the effects of tensile damage on the compressive behavior of concrete and vice-versa. This study presents a cyclic model established by extending an existing monotonic constitutive model. The model describes the cyclic behavior of concrete under multiaxial loading conditions and considers the influence of tensile/compressive damage on the compressive/tensile response. The proposed model, dubbed the enhanced concrete damage plasticity model (ECDPM), is an extension of an existing model that combines the theories of classical plasticity and continuum damage mechanics. Unlike most prior studies on models in the same category, the performance of the proposed ECDPM is evaluated using experimental data on concrete specimens at the material level obtained under cyclic multiaxial loading conditions including uniaxial tension and confined compression. The performance of the model is observed to be satisfactory. Furthermore, the superiority of ECDPM over three previously proposed constitutive models is demonstrated through comparisons with the results of a uniaxial tension-compression test and a virtual test.

关键词: damage plasticity model     plain concrete     cyclic loading     multiaxial loading conditions    

Anaerobic treatment of fresh leachate from a municipal solid waste incinerator by upflow blanket filter reactor

Pinjing HE, Min LI, Suyun XU, Liming SHAO,

《环境科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 404-411 doi: 10.1007/s11783-009-0149-6

摘要: This paper describes the feasibility of fresh leachate treatment by an upflow blanket filter (UBF). Through dilution and partial effluent recycling, the organic loading rates increased from 0.51to 14.56kg COD/(m·d), meanwhile the corresponding hydraulic retention time decreased from 9.0d to 3.6d. The reactor was able to achieve steady-state within 80d. Based on the distribution of COD fluxes in the process, it was concluded that anabolism was the main pathway of COD removal in the initial phase (1―33d), accounting for 57%―85% of total COD removed. As the anaerobic consortium of bacteria reached steady-state (after 70―86d), the majority of COD removed was transformed into methane, because the specific methane yield was close to the theoretical value (0.36L CH/(g COD)).

关键词: distribution of COD fluxes     effluent recycling     leachate     methane yield     organic loading rate     upflow blanket filter    

HY-2卫星激光观测精密定轨技术

王晓慧,彭海龙,林明森,周旭华,吴斌

《中国工程科学》 2014年 第16卷 第6期   页码 90-96

摘要: 本文较为详细地介绍了HY-2 卫星激光观测、轨道预报和激光跟踪系统(SLR)定轨技术,并对SLR定轨结果进行了初步检验。

关键词: 精密定轨     全球定位系统     多普勒雷达和无线电定位组合系统(DORIS)     卫星激光测距    

Comparison between inhibitor and uncoupler for minimizing excess sludge production of an activated sludge

CHEN Guowei, XI Pengge, XU Deqian, YU Hanqing

《环境科学与工程前沿(英文)》 2007年 第1卷 第1期   页码 63-66 doi: 10.1007/s11783-007-0012-6

摘要: In order to study the minimization of excess sludge production, the reduction in the excess sludge production in the presence of an inhibitor and uncoupler was studied in this work. The experimental results show that such an addition could effectively reduce the production of excess sludge. With the energy uncoupling model established in this work, energy uncoupling coefficient () was used to evaluate the reduction in excess sludge production. The energy uncoupling coefficients in the presence of dinitrophenol (dNP), Zn, and Cu was 0.75, 0.46, and 0.18, respectively. The analysis demonstrated that energy spilling occurred in the presence of dNP, and that dNP was an effective uncoupler for reducing the production of excess activated sludge without affecting the microbial respiration activity.

关键词: uncoupling coefficient     Cu     minimization     presence     uncoupling    

Effect of the addition of organic carbon sources on nitrous oxide emission in anaerobic-aerobic (low dissolved oxygen) sequencing batch reactors

Hongjing LI, Xiurong CHEN, Yinguang CHEN

《环境科学与工程前沿(英文)》 2010年 第4卷 第4期   页码 490-499 doi: 10.1007/s11783-010-0248-4

摘要: The effect of additional organic carbon sources on the production of nitrous oxide (N O) in anaerobic-aerobic (low dissolved oxygen) real wastewater treatment system was investigated. In this paper, three laboratory-scale sequencing batch reactors (SBRs) (SBR-1, SBR-2 and SBR-3) were operating under an anaerobic-aerobic (low dissolved oxygen, 0.15–0.45 mg·L ) configuration. The SBRs were ‘long-term cultured’ respectively with a single municipal wastewater sample, sodium acetate, and a waste-activated sludge alkaline fermentation liquid as the additional carbon sources of real wastewater. Off-gas analysis showed that N O was emitted into the atmosphere during the aerobic (low dissolved oxygen) period in the three SBRs, and the order of N O emission rate was SBR-2>SBR-1>SBR-3. It was observed that the higher poly-β-hydroxyvalerate fraction of polyhydroxyalkanoates, the lower glycogen transformation and less nitrite accumulation was in SBR-3, while the opposite behavior was observed in SBR-2. Further research indicated that the interaction of the factors above potentially affected the N O emission in the anaerobic-aerobic (low dissolved oxygen) system.

关键词: anaerobic-aerobic (low dissolved oxygen)     nitrous oxide (N2O) emitting rate     municipal wastewater     waste activated sludge     alkaline fermentation liquid    

标题 作者 时间 类型 操作

Continuous biohydrogen production from diluted molasses in an anaerobic contact reactor

Sheng CHANG, Jianzheng LI, Feng LIU

期刊论文

Start-up of PN-anammox system under low inoculation quantity and its restoration after low-loading rate

Guoliang Zhang, Liang Zhang, Xiaoyu Han, Shujun Zhang, Yongzhen Peng

期刊论文

Microbial community dynamics at high organic loading rates revealed by pyrosequencing during sugar refinery

Liguo Zhang, Qiaoying Ban, Jianzheng Li

期刊论文

Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

期刊论文

Achievement of high rate nitritation with aerobic granular sludge reactors enhanced by sludge recirculation

Zulkifly JEMAAT,Josep Anton TORA,Albert BARTROLI,Julián CARRERA,Julio PEREZ

期刊论文

Modification of the activated sludge model for chemical dosage

Shuai MA,Siyu ZENG,Xin DONG,Jining CHEN,Gustaf OLSSON

期刊论文

Reconsideration on the effect of nitrogen on mixed culture polyhydroxyalkanoate production toward high organic loading

Zhiqiang Chen, Lizhi Zhao, Ye Ji, Qinxue Wen, Long Huang

期刊论文

Concept and application of anaerobic suspended granular sludge bed (SGSB) reactor for wastewater treatment

Mingxia ZHENG,Zhong YAN,Jiane ZUO,Kaijun WANG

期刊论文

Performance of soft-hard-soft (SHS) cement based composite subjected to blast loading with consideration

Jun WU,Xuemei LIU

期刊论文

Shear-critical reinforced concrete columns under various loading rates

Witarto WITARTO,Liang LU,Rachel Howser ROBERTS,Y. L. MO,Xilin LU

期刊论文

enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial loading

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

期刊论文

Anaerobic treatment of fresh leachate from a municipal solid waste incinerator by upflow blanket filter reactor

Pinjing HE, Min LI, Suyun XU, Liming SHAO,

期刊论文

HY-2卫星激光观测精密定轨技术

王晓慧,彭海龙,林明森,周旭华,吴斌

期刊论文

Comparison between inhibitor and uncoupler for minimizing excess sludge production of an activated sludge

CHEN Guowei, XI Pengge, XU Deqian, YU Hanqing

期刊论文

Effect of the addition of organic carbon sources on nitrous oxide emission in anaerobic-aerobic (low dissolved oxygen) sequencing batch reactors

Hongjing LI, Xiurong CHEN, Yinguang CHEN

期刊论文